MEDIUM TEMPERATURE CO SHIFT CATALYST

TYPE

B110-2

USES

It is used for hydrogen manufacturing and ammonia synthesis unit to promote the reaction of converting CO with steam into H2 and CO2 at a higher temperature 300-500.

CO + H2O = CO2 + H2, H298 = 41.03 KJ/mol

Sulfur content is low in catalyst body. In operation, It releases sulfur fast. Especially used in processes which are not allowed to be polluted by sulfur after medium temperature shift, for example, decarbonation system which closely connected with low temperature shift and requires the gas not to be polluted by sulfur.

CHEMICAL COMPOSITIONS

Iron oxide (sulfur content <0.06%), chromium oxide, etc.

PHYSICAL PROPERTIES

Appearance: brown cylinder

Sizes: Φ(9.0-9.5) x (5.0-7.0) mm Special sizes can be supplied to meet the user’s requirements

Bulk density: 1.6 kg/L approximately

MEDIUM TEMPERATURE CO SHIFT CATALYST

TYPE

B110-2

INDUSTRIAL OPERATING CONDITIONS

Temperature: 300-500. Highest temperature allowed: <530

Space velocity of dry gas: 300-500 h-1 (atmospheric pressure)

600-1300 h-1 (raised pressure)

if pressure reached about 3 Mpa, the space velocity can reach 3000 h-1

Steam/gas ratio (in volume):0.6

Sulfur content in raw gas (by H2S): 0.1 g/Nm3

Oxygen content in raw gas: < 0.5%

Total solid content in circulating water of saturation tower: <500 ppm

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

MEDIUM TEMPERATURE CO SHIFT CATALYST

TYPE

B111

USES

It is used for catalytic process of converting CO with steam into H2 and CO2 in ammonia plants.

CO + H2O = CO2 + H2, H298 = 41.03 KJ/mol

It shows catalyst poison resistance is strong, and especially used in ammonia plants in which thick oil or bad coal containing high sulfur is used as raw materials.

CHEMICAL COMPOSITIONS

Iron oxide, chromium oxide, etc.

PHYSICAL PROPERTIES

Appearance: brown cylinder

Sizes: Φ(9.0-9.5) x (5.0-8.0) mm

Bulk density: 1.4-1.5 kg/L approximately

INDUSTRIAL OPERATING CONDITIONS

Temperature: 300-500. Normal operating temperature : 350-480

Space velocity of dry gas: 500-700 h-1 (atmospheric pressure)

Sulfur content in raw gas (by H2S): 5.0 g/Nm3

Oxygen content in raw gas: < 0.5%

Total solid content in circulating water of saturation tower: <500 ppm

MEDIUM TEMPERATURE CO SHIFT CATALYST

TYPE

B112

USES

It is used for catalytic process of converting CO with steam into H2 and CO2 in ammonia plants.

CO + H2O = CO2 + H2, H298 = 41.03 KJ/mol

The catalyst which is developed to suit for ammonia plants of high sulfur content in raw gas and is a lower temperature shift sulfur resistance catalyst. It can be used in all kinds of ammonia plants in middle or small scales. Especially used in ammonia plants in which conditions of gas desulfurization is bad and gas contains high H2S and organic sulfide. It can be also operated under the condition of lower temperature and lower steam/gas ratio.

CHEMICAL COMPOSITIONS

Iron oxide, chromium oxide and other special promoters..

PHYSICAL PROPERTIES

Appearance: brown cylinder

Sizes: Φ(9.0-9.5) x (5.0-8.0) mm

Bulk density: 1.4-1.6kg/L approximately

Specific surface: 50 m2/g approximately (reduced)

MEDIUM TEMPERATURE CO SHIFT CATALYST

TYPE

B112

INDUSTRIAL OPERATING CONDITIONS

Temperature: 290-480. Highest temperature allowed : 500

Space velocity of dry gas: 300-500 h-1 (atmospheric pressure)

600-1000 h-1 (raised pressure0.7Mpa)

Steam/gas ratio (in volume): 0.5

Sulfur content in raw gas (by H2S): ≤1.5 g/Nm3

Oxygen content in raw gas: < 0.5%

Total solid content in circulating water of saturation tower: <500 ppm

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

MEDIUM TEMPERATURE CO SHIFT CATALYST

TYPE

B115

USES

It is used for catalytic process of converting CO with steam into H2 and CO2 in ammonia plants.

CO + H2O = CO2 + H2, H298 = 41.03 KJ/mol

Low chromium-containing catalyst can be decrease pollution in catalyst preparation, operating process and used catalyst. It is used in ammonia synthesis plants in middle or small scales.

CHEMICAL COMPOSITIONS

Iron oxide, chromium oxide and other special promoters..

PHYSICAL PROPERTIES

Appearance: brown cylinder

Sizes: Φ(9.0-9.5) x (5.0-7.0) mm

Bulk density: 1.35-1.45kg/L approximately

Specific surface: 35 m2/g approximately (reduced)

MEDIUM TEMPERATURE CO SHIFT CATALYST

TYPE

B115

INDUSTRIAL OPERATING CONDITIONS

Temperature: 300-500

Space velocity of dry gas: 400-500 h-1 (atmospheric pressure)

800-1000 h-1 (raised pressure≥1 Mpa)

Steam/gas ratio (in volume): 0.7

Sulfur content in raw gas (by H2S): 1.2 g/Nm3

Oxygen content in raw gas: < 0.5%

Total solid content in circulating water of saturation tower: <500 ppm

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

MEDIUM TEMPERATURE CO SHIFT CATALYST

TYPE

B115

USES

It is used for catalytic process of converting CO with steam into H2 and CO2 in ammonia plants.

CO + H2O = CO2 + H2, H298 = 41.03 KJ/mol

Low chromium-containing catalyst can be decrease pollution in catalyst preparation, operating process and used catalyst. It is used in ammonia synthesis plants in middle or small scales.

CHEMICAL COMPOSITIONS

Iron oxide, chromium oxide and other special promoters..

PHYSICAL PROPERTIES

Appearance: brown cylinder

Sizes: Φ(9.0-9.5) x (5.0-7.0) mm

Bulk density: 1.35-1.45kg/L approximately

Specific surface: 35 m2/g approximately (reduced)

MEDIUM TEMPERATURE CO SHIFT CATALYST

TYPE

B115

INDUSTRIAL OPERATING CONDITIONS

Temperature: 300-500

Space velocity of dry gas: 400-500 h-1 (atmospheric pressure)

800-1000 h-1 (raised pressure≥1 Mpa)

Steam/gas ratio (in volume): 0.7

Sulfur content in raw gas (by H2S): 1.2 g/Nm3

Oxygen content in raw gas: < 0.5%

Total solid content in circulating water of saturation tower: <500 ppm

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

MEDIUM TEMPERATURE CO SHIFT CATALYST

TYPE

DG

USES

It is used for catalytic process of converting CO with steam into H2 and CO2 in ammonia plants.

CO + H2O = CO2 + H2, H298 = 41.03 KJ/mol

The catalyst is manufactured by special technique. It shows a low density and a high strength, the sulfur content in its body is low. Especial used in ammonia plants in large, middle or small scales. It is operated at a pressure about 3 Mpa.

CHEMICAL COMPOSITIONS

Iron oxide (sulfur content <0.06%), chromium oxide, etc.

PHYSICAL PROPERTIES

Appearance: brown cylinder

Sizes: Φ9.0 x (4.0-6.0) mm

Bulk density: 1.3 kg/L

Specific surface: 73.6 m2/g approximately (reduced)

INDUSTRIAL OPERATING CONDITIONS

Temperature: 290-500

 

AMMONIA SYNTHESIS CATALYST

TYPE

A106

USES

It is mainly used in ammonia industry. It can be also used in metallurgical and electronic industries to decompose ammonia into pure H2 and N2.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

CHEMICAL COMPOSITIONS

Fe3O4, K2O,AL2O3,CaO,SiO2, etc.

PHYSICAL PROPERTIES

Appearance: irregular magnetic particles with metallic luster

Sizes: 2.2-3.3 mm, 3.3-4.7 mm, 4.7-6.7 mm, 6.7-9.4 mm etc. Special sizes can be manufactured to meet the user’s requirements

Bulk density: varying with sizes, 2.8-3.0 kg/L

Specific surface: 16 m2/g approximately (reduced)

Iron ratio ( Fe 2+/Fe3+): 0.55-0.65

INDUSTRIAL OPERATING CONDITIONS

Temperature: 380-540; in normal, 420-515

Pressure: 10-58.8 Mpa

Space velocity: 10000-50000 h-1

 

AMMONIA SYNTHESIS CATALYST

TYPE

A109

USES

It is mainly used in ammonia industry. It can be also used in metallurgical and electronic industries to decompose ammonia into pure H2 and N2.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

CHEMICAL COMPOSITIONS

Fe3O4, K2O,AL2O3,CaO,SiO2 and MgO.

PHYSICAL PROPERTIES

Appearance: irregular magnetic particles with metallic luster

Sizes: 2.2-3.3 mm, 3.3-4.7 mm, 4.7-6.7 mm, 6.7-9.4 mm etc. Special sizes can be manufactured to meet the user’s requirements

Bulk density: varying with sizes, 2.8-3.0 kg/L

Specific surface: 18 m2/g approximately (reduced)

Iron ratio ( Fe 2+/Fe3+): 0.5-0.6

INDUSTRIAL OPERATING CONDITIONS

Temperature: 380-540; in normal, 420-515

Pressure: 10-58.8 Mpa

Space velocity: 10000-50000 h-1

 

AMMONIA SYNTHESIS CATALYST

TYPE

A110-1

USES

It is mainly used in ammonia industry.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

The catalyst is easy reduction, good activity at low temperature, heat and poison resistance is strong. Compared with A106, capacity of converter using A110-1 increases about ten percent. Tested by many international companies, it is regarded as one of the best catalyst in the world. At present, it is widely used in ammonia plants in middle or small scales, especially in axial-radial converter of Casale and radial converter of Topsøe with the capacity of 300000 t/a.

CHEMICAL COMPOSITIONS

Fe3O4, K2O,AL2O3 and BaO.

PHYSICAL PROPERTIES

Appearance: irregular magnetic particles with metallic luster

Sizes: 2.2-3.3 mm, 3.3-4.7 mm, 4.7-6.7 mm, 6.7-9.4 mm etc. Special sizes can be manufactured to meet the user’s requirements

Bulk density: varying with sizes, 2.8-3.0 kg/L

Specific surface: 18 m2/g approximately (reduced)

Iron ratio ( Fe 2+/Fe3+): 0.5-0.6

AMMONIA SYNTHESIS CATALYST

TYPE

A110-1

INDUSTRIAL OPERATING CONDITIONS

Temperature: 340-530; in normal, 460-500

Pressure: 10-58.8 Mpa

Space velocity: 10000-50000 h-1

 

 

 

 

 

 

 

 

 

 

 

 

 

AMMONIA SYNTHESIS CATALYST

TYPE

A110-1Q

USES

It is mainly used in ammonia industry. Compared with irregular same equiralent diameter catalyst, pressure drop for A110-1Q is less.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

CHEMICAL COMPOSITIONS

Fe3O4, K2O,AL2O3 , BaO,etc.

PHYSICAL PROPERTIES

Appearance: black spherical particles with metallic luster

Sizes: φ3.3-φ4.5mm, φ4.5-φ5.5mm, φ5.5-φ7.0mm, etc.

Bulk density: 2.6-2.8 kg/L

INDUSTRIAL OPERATING CONDITIONS

Temperature: 340-530; in normal, 460-500

Pressure: 10-60 Mpa

Space velocity: 10000-50000 h-1

 

 

 

 

AMMONIA SYNTHESIS CATALYST

TYPE

A110-1-H

USES

It is mainly used in ammonia industry.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

It is produced under the best condition of suiting requirement of catalyst properties in catalyst plant, the A110-1 in Oxidation form is reduced to active а-Fe, then surface is passivated to form FeO preserving membrane with oxygen by special method. The catalyst shows advantages of short period of reduction in operation and striking effect.

CHEMICAL COMPOSITIONS

The mainly component Fe3O4 reduced toа-Fe, and others are K2O,AL2O3 , BaO,etc.

PHYSICAL PROPERTIES

Appearance: grey-black in color,irregular magnetic particles with metallic

luster

Sizes: 1.5-3.0mm, 2.2-3.3 mm, 3.3-4.7 mm, 4.7-6.7 mm, 6.7-9.4 mm etc. Special sizes can be manufactured to meet the user’s requirements.

Bulk density: 2.1-2.3 kg/L

Specific surface: 13 m2/g approximately (reduced)

Porosity: 46%

AMMONIA SYNTHESIS CATALYST

TYPE

A110-1-H

INDUSTRIAL OPERATING CONDITIONS

Temperature: 340-530

Pressure: 10-58 Mpa

Space velocity: 10000-50000 h-1

 

 

 

 

 

 

 

 

 

 

 

 

 

AMMONIA SYNTHESIS CATALYST

TYPE

AC

USES

It is mainly used in ammonia industry.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

It is a energy-saving ammonia synthesis catalyst. Contains a little cobalt, the advantages of AC is easily reduction, good activity at low temperature,low operating pressure and high net value of ammonia conversion. Especially used in process of low pressure ammonia synthesis, and can be also used in new process of isobaric synthesis. We can supplied the prereduced product of AC.

PHYSICAL PROPERTIES

Appearance: black in color,irregular magnetic particles with metallic

luster

Sizes: 2.2-3.3 mm, 3.3-4.7 mm, 4.7-6.7 mm, 6.7-9.4 mm etc. Special sizes can be manufactured to meet the user’s requirements.

Bulk density: 2.8 kg/L approximately

INDUSTRIAL OPERATING CONDITIONS

Temperature: 340-500

Pressure: 10-58.8 Mpa

Space velocity: 10000-50000 h-1

AMMONIA SYNTHESIS CATALYST

TYPE

ACQ

USES

It is mainly used in ammonia industry.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

Manufactured to spherical form by special techniques. Compared with irregular and same equivalent diameter catalysts, the pressure drop of synthesis converter is less when using it. Its quality is meet the AC type catalyst’s requirements.

PHYSICAL PROPERTIES

Appearance: black in color, magnetic spherical particles with metallic

luster

Sizes: φ3.5-φ4.5mm, φ4.5-φ5.5mm, φ5.5-φ7.0mm, etc.

Bulk density: 2.6-2.8 kg/L

INDUSTRIAL OPERATING CONDITIONS

Temperature: 350-500

Pressure: 10-60 Mpa

Space velocity: 10000-50000 h-1

 

 

AMMONIA SYNTHESIS CATALYST

TYPE

74-1

USES

It is mainly used in ammonia industry.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

74-1 energy-saving catalyst manufactured by advanced techniques can combine H2 with N2 to form ammonia, and shows higher conversion rate at a low temperature, so energy consumption can be controlled in a better level. Quality of the catalyst has reached the world level.

CHEMICAL COMPOSITIONS

Fe3O4 and special promoters

PHYSICAL PROPERTIES

Appearance: black in color, irregular magnetic particles with metallic

luster

Sizes: 2.2-3.3 mm, 3.3-4.7 mm, 4.7-6.7 mm, 6.7-9.4 mm etc. Special sizes can be manufactured to meet the user’s requirements

Bulk density: varying with sizes, 2.6-3.0 kg/L

 

 

 

 

 

AMMONIA SYNTHESIS CATALYST

TYPE

74-1

INDUSTRIAL OPERATING CONDITIONS

74-1 catalyst can be operated at a low pressure of 8 Mpa and temperature of 460 below(in full capacity running plant, it can be operated better at 6 Mpa). Its conversion rate is similar to that under the traditional condition of pressure over 15 Mpa and temperature of 550, for example, it can be operated at inlet temperature of 380, heat point of 468 and pressure of 10.5 Mpa. In general, it can worked in a pressure of 8 Mpa to 14 Mpa.

 

 

 

 

 

 

 

 

 

AMMONIA SYNTHESIS CATALYST

TYPE

74-1-H

USES

It is used to ammonia plants in large,middle or small scales, especially in low pressure ammonia plants.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

The prereduced catalyst 74-1H was made of 74-1 oxidation form product which is prereduced to active а-Fe,and stabilization treatment by control. 74-1-H shows advantages of easily reduction, less flow matter in reduction and reduction period is much shortened.

CHEMICAL COMPOSITIONS

Active iron and special promoters

PHYSICAL PROPERTIES

Appearance: grey-black in color, irregular magnetic particles with metallic luster

Sizes: 2.2-3.3 mm, 3.3-4.7 mm, 4.7-6.7 mm, 6.7-9.4 mm etc.

Bulk density: 2.2 kg/L approximately

 

 

 

 

 

AMMONIA SYNTHESIS CATALYST

TYPE

74-1-H

INDUSTRIAL OPERATING CONDITIONS

74-1 catalyst can be operated at a low pressure of 8 Mpa and temperature of 460 below(in full capacity running plant, it can be operated better at 6 Mpa). Its conversion rate is similar to that under the traditional condition of pressure over 15 Mpa and temperature of 550, for example, it can be operated at inlet temperature of 380, heat point of 468 and pressure of 10.5 Mpa. In general, it can worked in a pressure of 8 Mpa to 14 Mpa.

 

 

 

 

 

 

 

 

 

AMMONIA SYNTHESIS CATALYST

TYPE

NCA

USES

It is widely used to ammonia plants in large,middle or small scales.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

Low pressure ammonia synthesis catalyst was developed by our plant, shows advantages of easily reduction, low pressure and temperature operation, good activity and high crush strength, etc.

CHEMICAL COMPOSITIONS

Fe3O4 and special promoters

PHYSICAL PROPERTIES

Appearance: black in color, irregular magnetic particles with metallic luster

Sizes: 2.2-3.3 mm, 3.3-4.7 mm, 4.7-6.7 mm, 6.7-9.4 mm etc. Special sizes can be manufactured to meet the user’s requirements

Bulk density: 2.6-2.8 kg/L approximately

INDUSTRIAL OPERATING CONDITIONS

Temperature: 350-500

Pressure: 8-35 Mpa

Space velocity: 10000-50000 h-1

METHANATION CATALYST

TYPE

J105

USES

It is used for hydrogenation reaction of a little carbon oxide in high hydrogen-containing gas to produce methanol in ammonia synthesis and other hydrogen manufacturing units.

N2 + 3H2 = 2NH3, H298 = 92 .44 KJ/mol

Low pressure ammonia synthesis catalyst was developed by our plant, shows advantages of easily reduction, low pressure and temperature operation, good activity and high crush strength, etc.

CHEMICAL COMPOSITIONS

Fe3O4 and special promoters

PHYSICAL PROPERTIES

Appearance: black in color, irregular magnetic particles with metallic luster

Sizes: 2.2-3.3 mm, 3.3-4.7 mm, 4.7-6.7 mm, 6.7-9.4 mm etc. Special sizes can be manufactured to meet the user’s requirements

Bulk density: 2.6-2.8 kg/L approximately

INDUSTRIAL OPERATING CONDITIONS

Temperature: 350-500

Pressure: 8-35 Mpa

Space velocity: 10000-50000 h-1